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Wei Liu, Yang Qu, Wei Zhou, Zhiyu Ren, Baojiang Jiang, Guofeng Wang, Le Jiang, Fulong Yuan* and Honggang Fu1*
Mixed-phase MgTiO3/MgTi2O5 microspheres were prepared through a salicylic acid precursor method and further calcined in air. The microspheres were formed through coordination, polymerization, and aggregation processes. Salicylic acid acted as a ligand in coordinating with metal ions, in addition to acting as a structure-directing agent in the polymerization and aggregation of the titanate precursor microspheres via chemical bonds and electrostatic attraction. The mixed-phase MgTiO3/ MgTi2O5 microspheres prepared by this method showed excellent photocatalytic hydrogen production efficiencies that were two and four times higher than mixed-phase nanoparticles and pure-phase nanoparticles, respectively, owing to their closed phase junctions and sphere-like morphologies. This versatile and facile salicylic acid precursor method was also used to prepare a number of other bivalent metal-based titanate microspheres, including BaTiO3, ZnTiO3, CoTiO3, NiTiO3, and CdTiO3.
INTRODUCTION
ATiO3-type (where A is a bivalent metal ion) perovskite titanates are key materials used in electronic devices, ceramics, solid oxide fuel cell electrodes, metal-air barriers, and gas sensors, owing to their outstanding electrical properties, chemical stability, and excellent dielectric loss constant [1–5]. Although these materials have been used for over 50 years, some unusual characteristics related to their photocatalytic properties have recently been discovered, which might lead to new applications in photoelectrochemistry and water splitting [6–8]. However, the limitations in material synthesis techniques and the lack of clear understanding of their electron structures hinder the exploitation of the full potential of titanates. Therefore, it is vital to develop new strategies for preparing highly efficient and functional nano-titanates and further study their electronic structures. Controlling the morphology of titanates is particularly important.
Microsphere-based functional materials have attracted great interest because of their potential for applications in a wide range of areas, such as drug delivery, photocatalysis, dye-sensitized solar cells, gas sensors, and lithium-ion batteries, as a result of their intrinsic optical properties, high surface area, low density, and anisotropy [9]. Inverse opalphotonic crystals assembled from microspheres are regarded as a bridge connecting artificial and natural materials. Such materials are utilized in chemical sensing, solar cells, and biosensing [10–12] applications. Microspherical materials have been demonstrated as key materials in energy and environment applications. Although a number of metal oxide microspheres have been prepared by various approaches such as hydrothermal techniques [13], Ostwald ripening [14], and solvothermal techniques [15], there are few reports on titanate microspheres, which may be due to the lack of availability of suitable synthesis methods. Conventional solid-state reactions that are used to prepare titanates usually yield products with large particle size, large amounts of impurities, and irregular morphologies. In addition, such reactions also require high sintering temperatures (> 1000°C) and long reaction times (> 6 h) [16,17]. Therefore, developing new synthesis strategies for titanate microspheres with low energy consumption, controlled reactions, and ease of use is a great challenge.
Coordination chemistry is among the most important branches of chemistry. Many functional materials such as metal-organic frameworks, dyes, and metal-based molecules have been synthesized based on the principles of coordination chemistry. By utilizing metal ions and ligands, it is easy to obtain a soft precursor for metal oxides or perovskites. The metal-ligand precursor formed by the coordination polymerization of metal acetate and an organic ligand is a natural soft source for metal oxides and titanates, because the metal-oxygen octahedral bridge formed by the cross-linking of metal ions and oxygen, can easily transform into metal-oxide units during calcination [18,19]. These soft metal-organic precursors could easily transform into titanates after annealing in air and the microsphere shape could be retained. The metal-ligand precursor route can significantly reduce the sintering temperature and reaction time to about 600 °C and 2 h, respectively, owing to the soft structure of the precursors [20]. However, the metal-ligand precursor method is restricted by ionic radius and other parameters. Therefore, a new and versatile method for preparing functional titanates is required.
In this context, we report a versatile method based on the salicylic acid (SA) medium for preparing ATiO3 (where A = Mg, Ba, Zn, Co, Ni, and Cd) microspheres. Through this method, sphere-like titanates could be obtained by using SA as a ligand. The metal-SA frameworks can be assembled through the conjugated π-π interactions of the benzene ring in SA and the hydrogen bond as described in the literature [21]. Mixed-phase magnesium titanates ( MgTiO3/MgTi2O5) are believed to be excellent photocatalysts for hydrogen production, owing to the natural phase junctions formed by the mixed-phase MgTiO3 and MgTi2O5 that could enhance charge separation [22].
EXPERIMENTAL SECTION
Synthesis
The typical synthesis procedure for titanate microspheres using the SA precursor method was as follows. Clear ethanol solution (40 mL) containing 0.01 mol of metal acetate (Mg, Ba, Zn, Co, Ni, and Cd), 0.01 mol of tetrabutyl titanate, and 0.01 mol of SA was transferred into a 50 mL Teflon-lined stainless-steel autoclave, which was then sealed and heated at 180°C for 12 h. After the solvothermal reaction, a precipitate containing the metal-SA precursor was obtained. The precursor was purified using three centrifugation and redispersion cycles with absolute ethanol and was dried under vacuum at 60°C for 4 h. The titanate microspheres were prepared by calcining the precursor in air at different temperatures for 2 h. The mixed-phase magnesium titanate samples were used for photocatalytic hydrogen production and were denoted as MT600, MT700, and MT800 for easy identification.
Characterization
X-ray powder diffraction (XRD) patterns were obtained using the Bruker D8XRD unit. Scanning electron microscopy (SEM) images were acquired using a Hitachi S-4800 instrument operating at 15 kV. Transmission electron microscopy (TEM) experiments were performed on a JEM-2100 electron microscope (JEOL, Japan) with an acceleration voltage of 200 kV. Carbon-coated copper grids were used as the sample holders. Pyrolysis of the metal-SA precursors was carried out in a thermogravimetry (TG) unit (TA, Q600) under a stream of air with a heating rate of 10°C min−1 . The specific surface area of the product was determined using the Brunauer-Emmett-Teller (BET) method using a Tristar II 3020 surface area and porosity analyzer (Micromeritics). UV-visible absorption spectra were recorded using a UV-visible spectrophotometer (SHIMADZU UV-2550).
Photocatalysis
The photocatalytic hydrogen production experiments were conducted in an online photocatalytic hydrogen production system (AuLight, Beijing, CEL-SPH2N) at ambient temperature (20ºC). The catalyst (0.1 g) was suspended in a mixture of distilled water (80 mL) and methanol (20 mL) in the reaction cell using a magnetic stirrer. Pt-loaded photocatalysts (1 wt.%) were prepared by a known standard in-situ photodeposition method using H2PtCl6 aqueous solution. Prior to the reaction, the mixture was deaerated by evacuation to remove the O2 and CO2 dissolved in water. The reaction was carried out by irradiating the mixture with UV light from a 300 W Xe lamp (AuLight, CEL-HXF300) with a UVREF filter (AuLight, 200-400 nm). Gas evolution was observed only under photoirradiation and the evolved gases were analyzed using an online gas chromatograph (SP7800, TCD, molecular sieve 5 Å, N2 carrier, Beijing Keruida Limited).